4-Chloro-N′-[(E)-2-chlorobenzylidene]benzohydrazide monohydrate

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4-Chloro-N′-[(E)-2-chloro­benzyl­idene]benzohydrazide monohydrate

The title compound, C14H10Cl2N2O·H2O, has a nearly planar extended conformation [C-N-N-C = -173.66 (15)°]. The dihedral angle between the aromatic rings is 4.6 (2)°. The water mol-ecules alternate with benzohydrazide mol-ecules in chains formed by O-H⋯O hydrogen bonds which run parallel to the a axis. These chains are linked to neighboring chains through N-H⋯O and C-H⋯O inter-actions, forming a...

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4-Chloro-N′-(2-hydroxy­benzyl­idene)benzohydrazide monohydrate

The asymmetric unit of the title compound, C(14)H(11)ClN(2)O(2)·H(2)O, contains a Schiff base mol-ecule and a water mol-ecule of crystallization. The dihedral angle between the two aromatic rings is 27.3 (4)°. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to the bc plane by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds involving the water mol-ecules.

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The mol-ecule of the title hydrate, C(16)H(11)ClFN(3)·H(2)O, is slightly twisted, as indicated by the dihedral angle of 9.55 (10)° formed between the quinoline ring system and the benzene ring. The conformation about the C=N double bond is E, and the amine-H atom is oriented towards the quinoline residue. In the crystal structure, the water mol-ecule accepts an N-H⋯O and makes two O-H⋯N(quinoli...

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The title compound, C(14)H(11)ClFN(3)O·H(2)O, exists in an E conformation with respect to the N=C bond. The pyridine ring forms a dihedral angle of 5.00 (9)° with the benzene ring. In the crystal, the ketone O atom accepts one O-H⋯O and one C-H⋯O hydrogen bond, the water O atom accepts one N-H⋯O and two C-H⋯O hydrogen bonds and the pyridine N atom accepts one O-H⋯N hydrogen bond, forming layers...

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(E)-N′-(2-Chloro-5-nitro­benzyl­idene)-3-meth­oxy­benzohydrazide monohydrate

In the hydrazone mol-ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6 (1)°. In the crystal structure, the solvent water mol-ecules are involved in the formation of inter-molecular N-H⋯O and O-H⋯N hydrogen bonds, which link the mol-ecules into double ribbons extending along the b axis. Inter-molecular π-π inter-actions between the aromat...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2014

ISSN: 1600-5368

DOI: 10.1107/s1600536814008885